Fundamentals of Diatomic Molecular Spectroscopy
نویسندگان
چکیده
The interpretation of optical spectra requires thorough comprehension quantum mechanics, especially understanding the concept angular momentum operators. Suppose now that a transformation from laboratory-fixed to molecule-attached coordinates, by invoking correspondence principle, induces reversed operator identities. However, foundations mechanics and mathematical implementation specific symmetries assert reversal motion or time includes complex conjugation as part anti-unitary operation. Quantum theory contraindicates sign changes fundamental algebra. Reversed are heuristic nature actually not needed in analysis diatomic spectra. This review addresses sustenance usual theory, including presentation straightforward proofs leading falsification occurrence also summarizes aspects consistent for spectroscopy with selected molecules interest astrophysics engineering applications.
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ژورنال
عنوان ژورنال: Foundations
سال: 2021
ISSN: ['2673-9321']
DOI: https://doi.org/10.3390/foundations1020016